(Peer-Reviewed) Hot electron electrochemistry at silver activated by femtosecond laser pulses
Oskar Armbruster ¹ ², Hannes Pöhl ², Wolfgang Kautek ²
¹ University of Natural Resources and Life Sciences, Vienna, Department of Bionanosciences, Muthgasse 11, 1190 Vienna, Austria
² University of Vienna, Department of Physical Chemistry, Währinger Straße 42, 1090 Vienna, Austria
Opto-Electronic Advances, 2023-06-25
Abstract
A silver microelectrode with a diameter of 30 µm in an aqueous K2SO4 electrolyte was irradiated with 55 fs and 213 fs laser pulses. This caused the emission of electrons which transiently charged the electrochemical double layer. The two applied pulse durations were significantly shorter than the electron-phonon relaxation time.
The laser pulse durations had negligible impact on the emitted charge, which is incompatible with multiphoton emission. On the other hand, the observed dependence of emitted charge on laser fluence and electrode potential supports the thermionic emission mechanism.
Genetic algorithm assisted meta-atom design for high-performance metasurface optics
Zhenjie Yu, Moxin Li, Zhenyu Xing, Hao Gao, Zeyang Liu, Shiliang Pu, Hui Mao, Hong Cai, Qiang Ma, Wenqi Ren, Jiang Zhu, Cheng Zhang
Opto-Electronic Science
2024-09-20
Surface-patterned chalcogenide glasses with high-aspect-ratio microstructures for long-wave infrared metalenses
Zhaofeng Gu, Yixiao Gao, Kongsi Zhou, Junyang Ge, Chen Xu, Lei Xu, Mohsen Rahmani, Ran Jiang, Yimin Chen, Zijun Liu, Chenjie Gu, Yaoguang Ma, Jianrong Qiu, Xiang Shen
Opto-Electronic Science
2024-09-03
Racemic dielectric metasurfaces for arbitrary terahertz polarization rotation and wavefront manipulation
Jie Li, Xueguang Lu, Hui Li, Chunyu Song, Qi Tan, Yu He, Jingyu Liu, Li Luo, Tingting Tang, Tingting Liu, Hang Xu, Shuyuan Xiao, Wanxia Huang, Yun Shen, Yan Zhang, Yating Zhang, Jianquan Yao
Opto-Electronic Advances
2024-08-28
